Browsing School of Chemistry (Scholarly Articles) by Title
Now showing items 64-83 of 347
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A comprehensive experimental and modeling study of isobutene oxidation
(Elsevier, 2016-03-17)Isobutene is an important intermediate in the pyrolysis and oxidation of higher-order branched alkanes, and it is also a component of commercial gasolines. To better understand its combustion characteristics, a series of ... -
A comprehensive experimental and modeling study of the ignition delay time characteristics of ternary and quaternary blends of methane, ethane, ethylene, and propane over a wide range of temperature, pressure, equivalence ratio, and dilution
(Elsevier, 2021-08-09)The ignition delay time (IDT) characteristics of new ternary and quaternary blended C 1 ¿C 3 gaseous hy- drocarbons, including methane/ethane/ethylene and methane/ethane/ethylene/propane, are studied over a wide range of ... -
A comprehensive experimental and simulation study of ignition delay time characteristics of single fuel C1–C2 hydrocarbons over a wide range of temperatures, pressures, equivalence ratios, and dilutions
(American Chemical Society, 2020-02-03)A comprehensive experimental and modeling study of the ignition delay time (IDT) characteristics of some single prominent C1–C2 hydrocarbons including methane, ethane, and ethylene has been performed over a wide range of ... -
Comprehensive experimental and simulation study of the ignition delay time characteristics of binary blended methane, ethane, and ethylene over a wide range of temperature, pressure, equivalence ratio, and dilution
(American Chemical Society, 2020-06-03)A comprehensive experimental and kinetic modeling study of the ignition delay time (IDT) characteristics of some binary blends of C1–C2 gaseous hydrocarbons such as methane/ethylene, methane/ethane, and ethane/ethylene was ... -
A comprehensive iso-octane combustion model with improved thermochemistry and chemical kinetics
(Elsevier, 2017-02-05)Iso-Octane (2,2,4-trimethylpentane) is a primary reference fuel and an important component of gasoline fuels. Moreover, it is a key component used in surrogates to study the ignition and burning characteristics of gasoline ... -
A comprehensive spectroscopic study of the polymorphs of diflunisal and their phase transformations
(Elsevier, 2017-06-08)Understanding phase transitions in pharmaceutical materials is of vital importance for drug manufacturing, processing and storage. In this paper we have carried out comprehensive high-resolution spectroscopic studies on ... -
Comprehensive, quantitative bioprocess productivity monitoring using fluorescence EEM spectroscopy and chemometrics
(Royal Society of Chemistry, 2014)This study demonstrates the application of fluorescence excitation-emission matrix (EEM) spectroscopy to the quantitative predictive analysis of recombinant glycoprotein production cultured in a Chinese hamster ovary (CHO) ... -
Conformations of myoglobin-derived peptides at the air-water interface
(American Chemical Society, 2016-04-14)The conformational change exhibited by proteins at liquid interfaces, such as the air-water and oil-water interfaces, has long been of interest, both for understanding protein structure outside of native environments and ... -
Controlling the pirouetting motion in rotaxanes by counterion exchange
(American Chemical Society, 2014-07-25)A fine control of the pirouetting motion of rotaxanes was achieved by using a series of metallabisdicarbollides. The latter were used as anions in the protonated form of benzylic amide macrocycle-containing fumaramide ... -
A convenient synthetic route to useful monobranched polyethoxylated halogen terminated [3,3 -Co(1,2-C2B9H11)2]- synthons
(Royal Society of Chemistry, 2009-11-15)An atom efficient and environmentally friendly route has been developed to obtain a new range of reagents in metallacarborane chemistry having monobranched polyethoxylated cobaltabisdicarbollide synthons. -
Conversion of gel-forming crystal needles to easily processable more equant crystals Using high-shear ultralow attrition agitation: accelerated Ostwald ripening without crystal attrition
(American Chemical Society, 2019-02-01)We demonstrate the first examples of the transformation of gel-forming crystal needles into easily processable more equant crystals by accelerated Ostwald ripening without detectable crystal attrition. Using high solution ... -
Cost-effective wireless microcontroller for internet connectivity of open-source chemical devices
(American Chemical Society, 2018-06-04)This paper presents a system for remote monitoring of turbidity data that can detect light intensity and temperature using a microcontroller and the Internet of Things. The system comprises a light dependent resistor and ... -
Critical evaluation of thermochemical properties of C-1-C-4 species: updated group-contributions to estimate thermochemical properties
(AIP Publishing, 2015-01-05)A review of literature on enthalpies of formation and molar entropies for alkanes, alkenes, alcohols, hydroperoxides, and their associated radicals has been compiled and critically evaluated. By comparing literature values, ... -
Crystalline adducts of the Lawsone molecule (2-hydroxy-1,4-naphthaquinone): optical properties and computational modelling
(Royal Society of Chemistry, 2015-09-04)Four new crystalline adducts of the Lawsone molecule (2-hydroxy-1,4-naphthaquinone) with 4,4'-bipyridine, 4-(2-pyridine-4-ethyl)pyridine, 1,3-di.4-pyridyl)propane and 2-hydroxy pyridine are reported. Adduct formation leads ... -
Crystallization of organic salts from the gas phase: When does proton transfer take place?
(American Chemical Society, 2020-12-13)Salt formation with proton transfer is observed in crystals grown by cosublimation of the salt coformers. Diflunisal salts were obtained with 4-[3-(pyridin-4-yl)propyl]pyridine, piperazine, and 4-dimethylaminopyridine. ... -
A Cu(II) complex targeting the translocator protein: in vitro and in vivo antitumor potential and mechanistic insights
(Royal Society of Chemistry, 2016-12-01)A new Cu-based anticancer metallodrug which targets the translocator protein is reported. [CuBr2(TZ6)] elicits a remarkable in vitro cytotoxicity in sensitive and multidrug resistant cell lines and induces a 98% reduction ... -
Cyclopentane combustion. Part II. Ignition delay measurements and mechanism validation
(Elsevier, 2017-06-12)This study reports cyclopentane ignition delay measurements over a wide range of conditions. The measurements were obtained using two shock tubes and a rapid compression machine, and were used to test a detailed low- and ... -
Cytotoxicity and antimicrobial activity of triorganotin(IV) complexes of phenylcyanamide prepared by sonochemical synthesis
(Elsevier, 2015-09-25)This article describes the synthesis and characterization of novel triorganotin(IV) complexes and their potential medicinal applications. Triorganotin(IV) complexes with formulas [(SnMe3)(2)(mu-bp)(H2O)(2)], 1, and ... -
Cytotoxicity and ROS production of novel Pt(IV) oxaliplatin derivatives with indole propionic acid
(Elsevier, 2019-04-19)The coordination of biologically active moieties to the axial positions of Pt(IV) derivatives of Pt(II) anticancer drugs allows the co-delivery and simultaneous activation of two pro-drugs for combination therapy. Pt(IV) ... -
Decomposition studies of isopropanol in a variable pressure flow reactor
(Oldenbourg Verlag, 2015-04-01)Alternatives to traditional petroleum derived transportation fuels, particularly alcohols, have been investigated increasingly over the last 5 years. Isopropanol has received little attention despite bridging the gap between ...