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dc.contributor.authorFarràs, Pau
dc.contributor.authorMusteti, Ana D.
dc.contributor.authorRojo, Isabel
dc.contributor.authorViñas, Clara
dc.contributor.authorTeixidor, Francesc
dc.contributor.authorLight, Mark E.
dc.date.accessioned2016-08-15T09:19:21Z
dc.date.available2016-08-15T09:19:21Z
dc.date.issued2014-05-12
dc.identifier.citationFarràs, Pau, Musteti, Ana D., Rojo, Isabel, Viñas, Clara, Teixidor, Francesc, & Light, Mark E. (2014). Widely Applicable Metallacarborane Reagents for π-Conjugated Systems. Inorganic Chemistry, 53(11), 5803-5809. doi: 10.1021/ic500615ken_IE
dc.identifier.issn1520-510X
dc.identifier.urihttp://hdl.handle.net/10379/5968
dc.description.abstractThe compounds [N(CH3)4][3,3′-Co(8-(p-C6H4C2H3)-1,2-C2B9H10)(1′,2′-C2B9H11)], [N(CH3)4][3,3′-Co(8-(p-C6H4CHO)-1,2-C2B9H10)(1′,2′-C2B9H11)], and [N(CH3)4][3,3′-Co(8-(m-C6H4CHO)-1,2-C2B9H10)(1′,2′-C2B9H11)] were synthesized using an easy methodology, in very good yields and large quantities, which are important requisites to be employed as starting reagents. They have been fully characterized by elemental analysis, IR, NMR, and MALDI-TOF-MS, and the crystal structures of [N(CH3)4][3,3′-Co(8-(p-C6H4C2H3)-1,2-C2B9H10)(1′,2′-C2B9H11)] and [N(CH3)4][3,3′-Co(8-(p-C6H4CHO)-1,2-C2B9H10)(1′,2′-C2B9H11)] were elucidated by single-crystal X-ray diffraction. These compounds, having terminal formyl and vinyl functional groups, are suitable platforms to involve the aromatic cobaltabisdicarbollide unit into extended π-conjugated systems. It is expected that these synthons will facilitate the applicability of metallacarboranes in a wide variety of different fields, where π-conjugated systems are needed to keep electronic communication.en_IE
dc.description.sponsorshipSpanish Ministry of Economy and Competitiveness (CTQ2010-16237), CSIC (I3P grant to P.F.) and the Generalitat de Catalunya (2009/SGR/00279). A.D.M. thanks the MICINN for an FPI granten_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherAmerican Chemical Societyen_IE
dc.relation.ispartofInorganic Chemistryen
dc.subjectChemistryen_IE
dc.subjectCobalten_IE
dc.subjectB-C couplingen_IE
dc.subjectCharge transferen_IE
dc.subjectCross-couplingen_IE
dc.subjectIsolobal relationshipen_IE
dc.subjectDyad systemsen_IE
dc.titleWidely applicable metallacarborane reagents for π-conjugated systemsen_IE
dc.typeArticleen_IE
dc.date.updated2016-08-10T16:56:09Z
dc.identifier.doi10.1021/ic500615k
dc.local.publishedsourcehttp:/dx.doi.org/10.1021/ic500615ken_IE
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funder|~|
dc.internal.rssid9451650
dc.local.contactPau Farras. Email: pau.farrascosta@nuigalway.ie
dc.local.copyrightcheckedNo
dc.local.versionPUBLISHED
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