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dc.contributor.authorRoeser, Stephen
dc.contributor.authorFarràs, Pau
dc.contributor.authorBozoglian, Fernando
dc.contributor.authorMartínez, Marta
dc.contributor.authorBenet-Buchholz, Jordi
dc.contributor.authorLlobet, Antoni
dc.date.accessioned2016-08-12T12:09:44Z
dc.date.available2016-08-12T12:09:44Z
dc.date.issued2011-01-27
dc.identifier.citationRoeser, S., Farràs, P., Bozoglian, F., Martínez-Belmonte, M., Benet-Buchholz, J. and Llobet, A. (2011), Chemical, Electrochemical, and Photochemical Catalytic Oxidation of Water to Dioxygen with Mononuclear Ruthenium Complexes. ChemSusChem, 4: 197–207. doi:10.1002/cssc.201000358en_IE
dc.identifier.issn1864-564X
dc.identifier.urihttp://hdl.handle.net/10379/5955
dc.description.abstractFour new RuII[BOND]Cl and RuII[BOND]H2O complexes containing the meridional 2,2’:6’,2”-terpyridine (trpy) ligand and the chelating 2-(5-phenyl-1H-pyrazol-3-yl)pyridine (H3p) ligand of general formula in- and out-[RuII(trpy)(H3p)(X)]n+ (X=Cl, n=1; X=H2O, n=2) have been prepared, isolated and thoroughly characterized both in solution and in the solid state. In solution, all the complexes are characterized spectroscopically by UV/Vis and NMR, and their redox properties investigated by means of cyclic voltammetry, square wave voltammetry, and coulometry. In the solid state, monocrystal X-ray diffraction analysis was carried out for the in and out Ru[BOND]Cl complexes. The capacity of the Ru-aqua complexes to act as water oxidation catalysts (WOCs) was also investigated chemically, electrochemically, and photochemically. The performance of these complexes has also been compared to two previously described complexes of general formula in- and out-[RuII(trpy)(Hbpp)(H2O)]2+ (Hbpp is 2,2′-(1H-pyrazole-3,5-diyl)dipyridine)), the capacity of which as WOCs had not been previously described.en_IE
dc.description.sponsorshipSOLAR-H2 (EU 212508) and MICINN (CTQ2010–21497 and Consolider Ingenio 2010 CSD2006–0003) are gratefully acknowledged. SR is grateful for the award of doctoral grant from MICINN.en_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherWileyen_IE
dc.relation.ispartofChemsuschemen
dc.subjectWater oxidationen_IE
dc.subjectRedox catalysisen_IE
dc.subjectRu complexesen_IE
dc.subjectRedox propertiesen_IE
dc.subjectChemistryen_IE
dc.titleChemical, electrochemical and photochemical catalytic oxidation of water to dioxygen with mononuclear ru complexesen_IE
dc.typeArticleen_IE
dc.date.updated2016-08-10T16:58:53Z
dc.identifier.doi10.1002/cssc.201000358
dc.local.publishedsourcehttp:/dx.doi.org/10.1002/cssc.201000358en_IE
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funder|~|
dc.internal.rssid9451805
dc.local.contactPau Farras. Email: pau.farrascosta@nuigalway.ie
dc.local.copyrightcheckedNo
dc.local.versionPUBLISHED
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