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dc.contributor.authorJones, Leigh F.
dc.date.accessioned2013-11-29T13:54:11Z
dc.date.available2013-11-29T13:54:11Z
dc.date.issued2012-09-05
dc.identifier.citationR. Inglis, C. Milios, L. F. Jones, S. Piligkos, E. K. Brechin (2012) 'Twisted Molecular Magnets'. Chem Comm, 48 :181-190.en_US
dc.identifier.issn1359-7345
dc.identifier.issnhttp://dx.doi.org/10.1039/C1CC13558A
dc.identifier.urihttp://hdl.handle.net/10379/3862
dc.descriptionJournal article (post-print)en_US
dc.description.abstractThe use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([MnIII6]) and thirty trinuclear ([MnIII3]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.en_US
dc.description.sponsorshipIRCSETen_US
dc.formatapplication/docen_US
dc.language.isoenen_US
dc.publisherRSCen_US
dc.relation.ispartofChem Commen
dc.subjectSingle-molecule magnetsen_US
dc.subjectMagneto-structural correlationsen_US
dc.titleTwisted molecular magnetsen_US
dc.typeArticleen_US
dc.date.updated2013-09-18T14:17:36Z
dc.local.publishedsourcehttp://dx.doi.org/10.1039/C1CC13558Aen_US
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funder|~|Other|~|
dc.internal.rssid2080072
dc.local.contactLeigh Fon Jones, School Of Chemistry, Room 133, Arts/Science Building, Nui Galway. 3462 Email: leigh.jones@nuigalway.ie
dc.local.copyrightcheckedNo
dc.local.versionACCEPTED
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