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Supramolecular stacking in a high Z′ calix[8]arene–porphyrin assembly

dc.contributor.authorAlex, Jimi M.
dc.contributor.authorMcArdle, Patrick
dc.contributor.authorCrowley, Peter B.
dc.date.accessioned2020-02-20T10:16:31Z
dc.date.issued2019-11-15
dc.identifier.citationAlex, Jimi M., McArdle, Patrick, & Crowley, Peter B. (2020). Supramolecular stacking in a high Z′ calix[8]arene–porphyrin assembly. CrystEngComm, 22(1), 14-17. doi: 10.1039/C9CE01646Een_IE
dc.identifier.issn1466-8033
dc.identifier.urihttp://hdl.handle.net/10379/15795
dc.description.abstractA co-crystal structure of sulfonato-calix[8]arene (sclx8) and trimethylanilinium-porphyrin (tmap) at 1.0 Å resolution is reported. The oppositely charged macrocycles formed an alternating stacked assembly. Crystal packing was completed by peripheral porphyrins that interlinked neighbouring stacks. Numerous cavities, presented by the calixarenes, were occupied by 2-methyl-2,4-pentanediol (the precipitant) resulting in an unusually high Z′.en_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherRoyal Society of Chemistryen_IE
dc.relation.ispartofCrystengcommen
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Ireland
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/ie/
dc.subjectSupramolecular stackingen_IE
dc.subjecthigh Z′ calix[8]arene–porphyrin assemblyen_IE
dc.titleSupramolecular stacking in a high Z′ calix[8]arene–porphyrin assemblyen_IE
dc.typeArticleen_IE
dc.date.updated2020-02-17T11:06:43Z
dc.identifier.doi10.1039/C9CE01646E
dc.local.publishedsourcehttps://doi.org/10.1039/C9CE01646Een_IE
dc.description.peer-reviewedpeer-reviewed
dc.description.embargo2020-11-15
dc.internal.rssid19875898
dc.local.contactPeter Bernard Crowley, Chemistry, Room 115, Arts/Science Building, Nui Galway. 2480 Email: peter.crowley@nuigalway.ie
dc.local.copyrightcheckedYes
dc.local.versionACCEPTED
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Ireland