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Metallacarboranes and their interactions: theoretical insights and their applicability
(Royal Society of Chemistry, 2012-02-14)
This tutorial review will deal with the study of metallacarboranes and their interactions with other molecules from a theoretical point of view. This contribution is devoted to guide experimental chemists through calculations ...
From icosahedron to a plane flattening dodecaiodo-dodecaborate by successive stripping of iodine
It has been shown by electrospray ionization–ion-trap mass spectrometry that B12I122− converts to an intact B12 cluster as a result of successive stripping of single iodine radicals or ions. Herein, the structure and ...