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Assessing the predictions of a NOx kinetic mechanism on recent hydrogen and syngas experimental data
(Elsevier, 2017-05-02)
A detailed chemical kinetic mechanism has been developed to describe the pyrolysis and oxidation of the hydrogen/NOx and syngas/NOx systems. The thermodynamic data of nitrogenous compounds have been updated based on the ...
An experimental and modelling study of n-pentane oxidation in two jet-stirred reactors: The importance of pressure-dependent kinetics and new reaction pathways
(Elsevier, 2016-06-16)
Two jet-stirred reactors (JSRs) coupled to gas chromatographic and spectroscopic techniques have been utilised to detect chemical species evolved during n -pentane oxidation at 1 and 10 atm, in the temperature range 500-1100 ...
Planar [Ni-7] discs as double-bowl, pseudo metallacalix[6]arene host cavities
(RSC, 2010-09-19)
We report three heptanuclear[Ni-7] complexes with planar disc-like cores, akin to double-bowl metallocalix[6]arenes, which form molecular H-bonded host cavities.
Effect of surface chemistry on islet amyloid polypeptide conformation
(American Institute of Physics, 2020-09-04)
The formation of dense, linear arrays (fibrils) by biomolecules is the hallmark of a number of degenerative diseases, such as Alzheimer s and type-2 diabetes. Protein fibrils have also attracted interest as building blocks ...
Low Temperature Fluorescence Studies of Crude Petroleum Oils
(2011)
We have studied the low-temperature (133-298 K) fluorescence emission of crude petroleum oils using a combination of steady-state and time-resolved measurements. This was done, first, to see if we could generate linear ...
Chemical, electrochemical and photochemical catalytic oxidation of water to dioxygen with mononuclear ru complexes
(Wiley, 2011-01-27)
Four new RuII[BOND]Cl and RuII[BOND]H2O complexes containing the meridional 2,2’:6’,2”-terpyridine (trpy) ligand and the chelating 2-(5-phenyl-1H-pyrazol-3-yl)pyridine (H3p) ligand of general formula in- and out-[RuII(tr ...
Morphological transitions in polymer vesicles upon bilayer swelling with small hydrophobic molecules in water
(Royal Society of Chemistry, 2013)
We show that when unilamellar polymer vesicles dispersed in water made from a blockcopolymer, in this case poly((ethylene oxide)45-block-(methyl methacrylate)164), poly((ethylene oxide)45-block-(methyl methacrylate)170), ...