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Surfactant behaviour of metallacarboranes. A study based on the electrolysis of water
(Royal Society of Chemistry, 2013-11-21)
[3,3′-Co(1,2-C2B9H11)2]−, [1]−, and its chloroderivatives have been described as displaying surfactant/aggregation properties. We have studied their behaviour as electrolytes in the water electrolysis process. The electrolysis ...
Additive tuning redox potential in metallacarboranes by sequencial halogen substitution
(Wiley, 2010-04-21)
The first artificially made set of electron acceptors is presented that are derived from a unique platform Cs[3,3′-Co(C2B9H11)2], for which the redox potential of each differs from its predecessor by a fixed amount. The ...