Browsing College of Science by Subject "Glycosyl thiols"
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Stereoselective epimerizations of glycosyl thiols
(American Chemical Society, 2017-10-17)Glycosyl thiols are widely used in stereoselective S-glycoside synthesis. Their epimerization from 1,2-trans to 1,2-cis thiols (e.g., equatorial to axial epimerization in thioglucopyranose) was attained using TiCl4, while ...