Browsing College of Science by Author "Farrell, Mark"
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Regiospecific anomerisation of acylated glycosyl azides and benzoylated disaccharides by using TiCl4.
Farrell, Mark; Zhou, Jian; Murphy, Paul V. (Wiley, 2013-10-25)Chelation induced anomerisation is promoted when Lewis acids, such as TiCl4 or SnCl4 , coordinate to the pyranose ring oxygen atom and another site, giving rise to endocyclic cleavage and isomerisation to the more stable ...