Browsing College of Science by Author "Coleman, Fergal"
Now showing items 1-2 of 2
-
Ga-III Complexes as Models for the M-III Site of Purple Acid Phosphatase: Ligand Effects on the Hydrolytic Reactivity Toward Bis(2,4-dinitrophenyl) phosphate
Erxleben, Andrea; Coleman, Fergal; Hynes, Michael (2010)The effects of a series of Galli complexes with tripodal ligands on the hydrolysis rate of the activated phosphate diester bis(2,4-dinitrophenyl)phosphate (BDNPP) have been investigated. In particular, the influence of the ... -
Rapid hydrolysis of phosphate monoesters by zirconium(IV) complexes in neutral solution
Erxleben, Andrea; Coleman, Fergal (2012)Three zirconium(IV) complexes (1-3) with mono- and dinucleating tripodal ligands are reported that promote the hydrolysis of the phosphate monoesters p-nitrophenyl phosphate (NPP) and phenyl phosphate (PP) in neutral ...