Browsing School of Chemistry by Author "Šícha, Václav"
Now showing items 1-2 of 2
-
Syntheses of C-substituted icosahedral dicarbaboranes bearing the 8-dioxane-cobalt bisdicarbollide moiety
Šícha, Václav; Farràs, Pau; Štíbr, Bohumil; Teixidor, Francesc; Grüner, Bohumir; Viñas, Clara (Elsevier, 2009-11-20)The treatment of 1,2-, 1,7- and 1,12-carbaborane lithiated isomers with [3,3′-Co-8-(CH2CH2O)2-(1,2-C2B9H10)-(1′,2′-C2B9H11)] (1) at molar ratios 1:1 or 1:2 at room temperature in THF leads generally to the formation of a ... -
Towards the synthesis of high boron content polyanionic multicluster macromolecules
Farràs, Pau; Cioran, Ana Maria; Šícha, Václav; Teixidor, Francesc; Štíbr, Bohumil; Grüner, Bohumír; Viñas, Clara (American Chemical Society, 2009-07-31)Reported are further consequences of the dioxane ring-opening in [3,3’-Co(8-(CH2CH2O)2-1,2-C2B9H10)(1’,2’-C2B9H11)] [1] with twelve-vertex carborane mono- and dianions. The removal of one BH vertex from the 1,2-carborane ...