Browsing School of Chemistry by Author "http://dx.doi.org/10.13039/501100007601"
Now showing items 1-6 of 6
-
Bioelectrochemical Haber-Bosch process: An ammonia-producing H-2/N-2 fuel cell
Milton, Ross D.; Cai, Rong; Abdellaoui, Sofiene; Leech, Dónal; De Lacey, Antonio L.; Pita, Marcos; Minteer, Shelley D. (Wiley, 2017-02-03)Nitrogenases are the only enzymes known to reduce molecular nitrogen (N-2) to ammonia (NH3). By using methyl viologen (N, N'-dimethyl-4,4'-bipyridinium) to shuttle electrons to nitrogenase, N-2 reduction to NH3 can be ... -
Combustion of n-C3–C6 linear alcohols: An experimental and kinetic modeling study. Part I: Reaction classes, rate rules, model lumping, and validation
Pelucchi, M.; Namysl, S.; Ranzi, E.; Rodriguez, A.; Rizzo, C.; Somers, K. P.; Zhang, Y.; Herbinet, O.; Curran, Henry J.; Battin-Leclerc, F.; Faravelli, T. (American Chemical Society, 2020-10-27)This work (and the companion paper, Part II) presents new experimental data for the combustion of n-C3–C6 alcohols (n-propanol, n-butanol, n-pentanol, n-hexanol) and a lumped kinetic model to describe their pyrolysis and ... -
Combustion of n-C3–C6 linear alcohols: An experimental and kinetic modeling study. Part II: Speciation measurements in a jet-stirred reactor, ignition delay time measurements in a rapid compression machine, model validation, and kinetic analysis
Pelucchi, M.; Namysl, S.; Ranzi, E.; Rodriguez, A.; Rizzo, C.; Somers, K. P.; Zhang, Y.; Herbinet, O.; Curran, Henry J.; Battin-Leclerc, F.; Faravelli, T. (American Chemical Society, 2020-10-27)This work presents new experimental data for n-C3–C6 alcohol, combustion (n-propanol, n-butanol, n-pentanol, n-hexanol). Speciation measurements have been carried out in a jet-stirred reactor (p = 107 kPa, T = 550–1100 K, ... -
Electrochemical glucose biosensor based on an osmium redox polymer and glucose oxidase grafted to carbon nanotubes: A design-of-experiments optimisation of current density and stability
Jayakumar, Kavita; Bennett, Richard; Leech, Dónal (Elsevier, 2021-01-25)Enzymatic glucose electrodes based on mediated electron transfer have potential for application as semi-implantable or implantable sensors. Enzyme electrodes consisting of adsorbed osmium-based redox polymer crosslinked ... -
The in vivo potential-regulated protective protein of nitrogenase in azotobacter vinelandii supports aerobic bioelectrochemical dinitrogen reduction in vitro
Milton, Ross D.; Cai, Rong; Sahin, Selmihan; Abdellaoui, Sofiene; Alkotaini, Bassam; Leech, Dónal; Minteer, Shelley D. (American Chemical Society, 2017-06-08)Nitrogenase, the only enzyme known to be able to reduce dinitrogen (N-2) to ammonia (NH3), is irreversibly damaged upon exposure to molecular oxygen (O-2). Several microbes, however, are able to grow aerobically and ... -
Probing sulfatide-tissue lectin recognition with functionalized glycodendrimersomes
Murphy, Paul V.; Romero, Antonio; Xiao, Qi; Ludwig, Anna-Kristin; Jogula, Srinivas; Shilova, Nadezhda V.; Singh, Tanuja; Gabba, Adele; Javed, Bilal; Zhang, Dapeng; Medrano, Francisco J.; Kaltner, Herbert; Kopitz, Jürgen; Bovin, Nicolai V.; Wu, Albert M.; Klein, Michael L.; Percec, Virgil; Gabius, Hans-Joachim (Cell Press, 2021-01-22)The small 3-O-sulfated galactose head group of sulfatides, an abundant glycosphingolipid class, poses the (sphinx-like) riddle on involvement of glycan bridging by tissue lectins (sugar code). First, synthesis of head group ...