Show simple item record

dc.contributor.authorHawkins, Gerard
dc.contributor.authorZetterlund, Per B.
dc.contributor.authorAldabbagh, Fawaz
dc.date.accessioned2016-04-27T10:42:16Z
dc.date.issued2015-05-13
dc.identifier.citationGerard Hawkins, Per B. Zetterlund, Fawaz Aldabbagh (2015) 'RAFT polymerization in supercritical carbon dioxide based on an induced precipitation approach: Synthesis of 2-ethoxyethyl methacrylate/acrylamide block copolymers'. Journal Of Polymer Science Part A-Polymer Chemistry, 53 :2351-2356.en_IE
dc.identifier.issn1099-0518
dc.identifier.urihttp://hdl.handle.net/10379/5721
dc.description.abstractA new controlled/living heterogeneous polymerization technique using RAFT in benign supercritical CO2 is described involving the formation of monomer-swollen seed particles by precipitation of macroRAFT agent prior to polymerization. Controlled/living character of the induced precipitation is compared with the equivalent solution polymerization. The large scale synthesis of poly(2-ethoxyethyl methacrylate)-b-poly(acrylamides) useful for biomedical applications is made possible with the polymer isolated as powders at high conversions, thus circumventing the requirement for volatile organic solvents. (c) 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2351-2356en_IE
dc.description.sponsorshipNUI Galway and Science Foundation Ireland (Research Infrastructure Call 2012)en_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherWileyen_IE
dc.relation.ispartofJournal Of Polymer Science Part A-Polymer Chemistryen
dc.subjectDispersionsen_IE
dc.subjectGreen chemistryen_IE
dc.subjectLiving polymerizationen_IE
dc.subjectPolyacrylamidesen_IE
dc.subjectRadical polymerizationen_IE
dc.subjectCatalyzed dispersion polymerizationen_IE
dc.subjectMethyl methacrylateen_IE
dc.subjectFragmentationen_IE
dc.subjectStyreneen_IE
dc.subjectLimiten_IE
dc.subjectCH13en_IE
dc.subjectChemistryen_IE
dc.titleRAFT polymerization in supercritical carbon dioxide based on an induced precipitation approach: synthesis of 2-ethoxyethyl methacrylate/acrylamide block copolymersen_IE
dc.typeArticleen_IE
dc.date.updated2016-04-27T09:19:14Z
dc.identifier.doi10.1002/pola.27688
dc.local.publishedsourcehttp://onlinelibrary.wiley.com/doi/10.1002/pola.27688/fullen_IE
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funder|~|
dc.description.embargo2016-05-13
dc.internal.rssid9874485
dc.local.contactFawaz Aldabbagh, Dept. Of Chemistry, Room 111, Arts/Science Building, Nui Galway. 3120 Email: fawaz.aldabbagh@nuigalway.ie
dc.local.copyrightcheckedNo
dc.local.versionACCEPTED
nui.item.downloads188


Files in this item

Attribution-NonCommercial-NoDerivs 3.0 Ireland
This item is available under the Attribution-NonCommercial-NoDerivs 3.0 Ireland. No item may be reproduced for commercial purposes. Please refer to the publisher's URL where this is made available, or to notes contained in the item itself. Other terms may apply.

The following license files are associated with this item:

Thumbnail

This item appears in the following Collection(s)

Show simple item record