Synthesis of α-galactosyl ceramide analogues with an α-triazole at the anomeric carbon
Date
2014-03-16Author
McDonagh, Anthony W.
Murphy, Paul V.
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McDonagh, AW,Murphy, PV (2014) 'Synthesis of α-galactosyl ceramide analogues with an α-triazole at the anomeric carbon'. Tetrahedron, 70 :3191-3196.
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Abstract
The synthesis of 1,2,3-triazole containing analogues of a-GalCer and galacturonic acid containing Sphingomonous cell wall antigens is described. Anomerisation was used to provide the required cc-glycosyl azide precursor. Copper azide alkyne cydoaddition (CuAAC) generated the a-triazole linkage. (c) 2014 Elsevier Ltd. All rights reserved.