dc.contributor.author | Meally, Sean T. | |
dc.contributor.author | McDonald, Cecelia | |
dc.contributor.author | Dunne, Peter W. | |
dc.contributor.author | McArdle, Patrick | |
dc.contributor.author | Jones, Leigh F. | |
dc.date.accessioned | 2013-11-29T15:31:49Z | |
dc.date.available | 2013-11-29T15:31:49Z | |
dc.date.issued | 2010-03-10 | |
dc.identifier.citation | Meally, S. T., McDonald, C., Karotsis, G., Papaefstathiou, G. S., Brechin, E. K., Dunne, P. W., et al. A family of double-bowl pseudo metallocalix[6]arene discs. Dalton Transactions, 39(20), 4809-4816. | en_US |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://pubs.rsc.org/en/content/articlelanding/2010/dt/b926704b#!divAbstract | |
dc.identifier.uri | http://hdl.handle.net/10379/3865 | |
dc.description | Journal article (post-print) | en_US |
dc.description.abstract | We report the synthesis and magnetic characterisation of a series of planar [M7] (M = NiII, ZnII) disc complexes [Ni7(OH)6(L1)6](NO3)2 (1), [Ni7(OH)6(L1)6](NO3)2·2MeOH (2), [Ni7(OH)6(L1)6](NO3)2·3MeNO2 (3), [Ni7(OH)6(L2)6](NO3)2·2MeCN (4), [Zn7(OH)6(L1)6](NO3)2·2MeOH·H2O (5) and [Zn7(OH)6(L1)6](NO3)2·3MeNO2 (6) (where HL1 = 2-iminomethyl-6-methoxy-phenol, HL2 = 2-iminomethyl-4-bromo-6-methoxy-phenol). Each member exhibits a double-bowl pseudo metallocalix[6]arene topology whereby the individual [M7] units form molecular host cavities which are able to accommodate various guest molecules (MeCN, MeNO2 and MeOH). Magnetic susceptibility measurements carried out on complexes 1 and 4 indicate weak exchange between the NIII centres. | en_US |
dc.description.sponsorship | IRCSET | en_US |
dc.format | application/pdf | en_US |
dc.language.iso | en | en_US |
dc.publisher | RSC | en_US |
dc.relation.ispartof | Dalton Transactions | en |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Ireland | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ie/ | |
dc.subject | Metallocalix[6]arenes | en_US |
dc.subject | Molecular magnetism | en_US |
dc.title | A family of double-bowl pseudo metallocalix[6]arene discs | en_US |
dc.type | Article | en_US |
dc.date.updated | 2013-09-18T14:17:46Z | |
dc.identifier.doi | http://pubs.rsc.org/en/content/articlelanding/2010/dt/b926704b#!divAbstract | |
dc.local.publishedsource | http://dx.doi.org/10.1039/B926704B | en_US |
dc.description.peer-reviewed | peer-reviewed | |
dc.contributor.funder | |~|IRCSET|~|Millennium Fund|~| | |
dc.internal.rssid | 5029053 | |
dc.local.contact | Leigh Fon Jones, School Of Chemistry, Room 133, Arts/Science Building, Nui Galway. 3462 Email: leigh.jones@nuigalway.ie | |
dc.local.copyrightchecked | No | |
dc.local.version | ACCEPTED | |
nui.item.downloads | 725 | |