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dc.contributor.authorMeally, Sean T.
dc.contributor.authorMcDonald, Cecelia
dc.contributor.authorKealy, Patrick
dc.contributor.authorJones, Leigh F.
dc.date.accessioned2013-11-29T12:54:52Z
dc.date.available2013-11-29T12:54:52Z
dc.date.issued2012
dc.identifier.citationMeally, ST,McDonald, C,Kealy, P,Taylor, SM,Brechin, EK,Jones, LF (2012) 'Investigating the solid state hosting abilities of homo- and hetero-valent [Co-7] metallocalix[6]arenes'. Dalton Transactions, 41 :5610-5616.en_US
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/10379/3861
dc.descriptionJournal article (post-print)en_US
dc.description.abstractA family of homo-valent [Co(II)(7)(OH)(6)(L-1)(6)](NO3)(2)(1), [(MeOH)(2)subset of Co(II)(7)(OH)(6)(L-1)(6)](NO3)(2) (2) (where L1H = 2-iminomethyl-6-methoxyphenol) and hetero-valent [(NO3)(2)subset of Co(III)Co(II)(6)(OH)(6)(L-2)(6)]-(NO3)center dot 3MeCN (4) (where L2H = 2-iminophenyl-6-methoxyphenol) complexes possess metallic skeletons describing planar hexagonal discs. Their organic exteriors form double-bowl shaped topologies, and coupled with their 3-D connectivity, this results in the formation of molecular cavities in the solid state. These confined spaces are shown to behave as host units in the solid state for guests including solvent molecules and charge balancing counter anions. Magnetic susceptibility measurements on 2 and 4 reveal weak ferro-and ferrimagnetism, respectively. The utilisation of other Co(II) salt precursors gives rise to entirely different species including the mononuclear and trinuclear complexes [Co(II)(L-2)(2)] (5) and [Co(III)(2)Na(I)(1)(L-3)(6)](BF4) (6) (where L3H = 2-iminomethyl-4-bromo-6-methoxyphenol).en_US
dc.description.sponsorshipIRCSETen_US
dc.formatapplication/pdfen_US
dc.language.isoenen_US
dc.publisherRSCen_US
dc.relation.ispartofDalton Transactionsen
dc.subjectGuest encapsulationen_US
dc.subjectMagnetic propertiesen_US
dc.subjectCrystal structureen_US
dc.subjectAqueous mediaen_US
dc.subjectCobalten_US
dc.subjectComplexesen_US
dc.subjectCoordinationen_US
dc.subjectClustersen_US
dc.subjectMoleculeen_US
dc.subjectChlorideen_US
dc.titleInvestigating the solid state hosting abilities of homo- and hetero-valent [Co-7] metallocalix[6]arenesen_US
dc.typeArticleen_US
dc.date.updated2013-09-18T14:17:19Z
dc.identifier.doiDOI 10.1039/c2dt12229d
dc.local.publishedsourcehttp://dx.doi.org/10.1039/C2DT12229Den_US
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funder|~|
dc.internal.rssid2195566
dc.local.contactLeigh Fon Jones, School Of Chemistry, Room 133, Arts/Science Building, Nui Galway. 3462 Email: leigh.jones@nuigalway.ie
dc.local.copyrightcheckedNo
dc.local.versionACCEPTED
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