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dc.contributor.authorHennessey, Seán
dc.contributor.authorFarràs, Pau
dc.contributor.authorBenet-Buchholz, Jordi
dc.contributor.authorLlobet, Antoni
dc.date.accessioned2020-03-10T13:21:42Z
dc.date.issued2019-11-05
dc.identifier.citationHennessey, Seán, Farràs, Pau, Benet-Buchholz, Jordi, & Llobet, Antoni. (2019). A Bpp-based dinuclear ruthenium photocatalyst for visible light-driven oxidation reactions. Catalysis Science & Technology, 9(23), 6760-6768. doi: 10.1039/C9CY01796Hen_IE
dc.identifier.issn2044-4761
dc.identifier.urihttp://hdl.handle.net/10379/15841
dc.description.abstractA diruthenium dyad molecule consisting of a 2,2-(1H-pyrazole-3,5-diyl)dipyridine (Hbpp) bridging ligand with the formula out-/in-[(bpy)2Ru(bpp)Ru(L)(tpy)]n+ (bpy = 2,2′-bipyridine, tpy = 2,2′:6′,2′′-terpyridine, L = Cl, CF3COO−, H2O or CH3CN and n = 2 or 3) has been prepared and fully characterised. The complex has been characterized by analytical and spectroscopic techniques and by X-ray diffraction analysis for two of the derivatives (Cl and CH3CN). Additionally, full electrochemical characterization based on cyclic voltammetry and square wave voltammetry has been also performed. The pH dependence of the redox couples for the aqua complex has also been studied and the corresponding Pourbaix diagram drawn. Furthermore, the capacity to photo-catalytically oxidize organic substrates, such as alcohols, alkenes, and sulfides, has been carried out and the overall stability and selectivity of the catalyst has been analysed.en_IE
dc.description.sponsorshipSupport from MINECO (CTQ2010-21497), Generalitat de Catalunya, and “la Caixa” Foundation are gratefully acknowledged. SH acknowledges support from College of Science scholarship, NUI Galway. PF acknowledges support from Royal Society Newton Alumni programme.en_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherRoyal Society of Chemistryen_IE
dc.relation.ispartofCatalysis Science & Technologyen
dc.subjectBpp-baseden_IE
dc.subjectdinuclear ruthenium photocatalysten_IE
dc.subjectlight-driven oxidation reactionsen_IE
dc.titleA Bpp-based dinuclear ruthenium photocatalyst for visible light-driven oxidation reactionsen_IE
dc.typeArticleen_IE
dc.date.updated2020-03-10T13:08:38Z
dc.identifier.doi10.1039/C9CY01796H
dc.local.publishedsourcehttps://doi.org/10.1039/C9CY01796Hen_IE
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funderMINECOen_IE
dc.contributor.funderGeneralitat de Catalunyaen_IE
dc.contributor.funder"La Caixa” Foundationen_IE
dc.contributor.funderCollege of Science, National University of Ireland, Galwayen_IE
dc.contributor.funderRoyal Society Newton Alumni programmeen_IE
dc.description.embargo2020-11-05
dc.internal.rssid19636612
dc.local.contactPau Farras, -. -- Email: pau.farrascosta@nuigalway.ie
dc.local.copyrightcheckedYes
dc.local.versionACCEPTED
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