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dc.contributor.authorCusack, Patricia B.
dc.contributor.authorCourtney, Ronan
dc.contributor.authorHealy, Mark G.
dc.contributor.authorO’ Donoghue, Lisa M.T.
dc.contributor.authorUjaczki, Éva
dc.date.accessioned2018-10-19T08:35:16Z
dc.date.issued2018-10-09
dc.identifier.citationCusack, Patricia B., Courtney, Ronan, Healy, Mark G., O’ Donoghue, Lisa M. T., & Ujaczki, Éva. (2019). An evaluation of the general composition and critical raw material content of bauxite residue in a storage area over a twelve-year period. Journal of Cleaner Production, 208, 393-401. doi: https://doi.org/10.1016/j.jclepro.2018.10.083en_IE
dc.identifier.issn1879-1786
dc.identifier.urihttp://hdl.handle.net/10379/14624
dc.description.abstractBauxite residue, the by-product produced in the alumina industry, is being produced at an estimated global rate of approximately 150 million tonnes per annum. Currently, the reuse of bauxite residue is low (∼2%), due to limitations associated with its alkalinity, salinity, low solid content, fine particle size and potential leaching of metal(loid)s. It has been identified as a potential secondary source for critical raw materials such as vanadium, gallium and scandium, which currently have an associated supply risk and high economic cost within Europe. However, there is an uncertainty regarding the possible variation in these and other physico-chemical, elemental and mineralogical parameters within bauxite residue disposal areas. This paper aimed to address this knowledge gap by examining the variation of these parameters in a bauxite residue disposal area (BRDA) over a twelve-year period. The general composition did not vary greatly within the bauxite residue examined, with the exception of pH and electrical conductivity, which ranged from 10 ± 0.1 to 12.0 ± 0.02 and from 0.4 ± 0.01 to 3.3 ± 0.2 mS cm−1, respectively. The bauxite residue contained critical raw materials, of which the amount of vanadium, gallium and scandium did not vary significantly over time. The vanadium and gallium were present in larger amounts compared to other European bauxite residues. On average the vanadium, gallium and scandium content measured in the bauxite residue samples were 510 ± 77.8, 107 ± 7.3 and 51.4 ± 5.4 mg kg−1, respectively. This shows promise for the potential reuse of bauxite residue as a secondary source for critical raw materials and also indicates that BRDAs may be potential mines for critical raw material extraction.en_IE
dc.description.sponsorshipThe authors would like to acknowledge the financial support of the Environmental Protection Agency (EPA) (2014-RE-MS-1).en_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherElsevieren_IE
dc.relation.ispartofJournal Of Cleaner Productionen
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Ireland
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/ie/
dc.subjectBauxiteen_IE
dc.subjectResidueen_IE
dc.subjectCircular economyen_IE
dc.subjectcrmen_IE
dc.subjectMetalsen_IE
dc.subjectCritical raw materialsen_IE
dc.titleAn evaluation of the general composition and critical raw material content of bauxite residue in a storage area over a twelve-year perioden_IE
dc.typeArticleen_IE
dc.date.updated2018-10-19T07:25:01Z
dc.identifier.doi10.1016/j.jclepro.2018.10.083
dc.local.publishedsourcehttps://doi.org/10.1016/j.jclepro.2018.10.083en_IE
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funderEnvironmental Protection Agencyen_IE
dc.description.embargo2020-10-09
dc.internal.rssid14767934
dc.local.contactMark Healy, Room Eng-1038, Civil Engineering, Col Of Engineering & Informatics, Nui Galway. 5364 Email: mark.healy@nuigalway.ie
dc.local.copyrightcheckedYes
dc.local.versionACCEPTED
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