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Experimental and kinetic modeling study of 2-methyl-2-butene: allylic hydrocarbon kinetics
(American Chemical Society, 2015-03-20)
Two experimental studies have been carried out on the oxidation of 2-methyl-2-butene, one measuring ignition delay times behind reflected shock waves in a stainless steel shock tube, and the other measuring fuel, intermediate, ...
Decomposition studies of isopropanol in a variable pressure flow reactor
(Oldenbourg Verlag, 2015-04-01)
Alternatives to traditional petroleum derived transportation fuels, particularly alcohols, have been investigated increasingly over the last 5 years. Isopropanol has received little attention despite bridging the gap between ...
Critical evaluation of thermochemical properties of C-1-C-4 species: updated group-contributions to estimate thermochemical properties
(AIP Publishing, 2015-01-05)
A review of literature on enthalpies of formation and molar entropies for alkanes, alkenes, alcohols, hydroperoxides, and their associated radicals has been compiled and critically evaluated. By comparing literature values, ...
Experimental and kinetic modeling study of the shock tube ignition of a large oxygenated fuel: tri-propylene glycol mono-methyl ether
(Elsevier, 2015-05-13)
Tri-propylene glycol monomethyl ether (TPGME) is an important oxygenated fuel additive that can be used to reduce soot in diesel engines. However, a validated chemical kinetic model that incorporates the low- to high-temperature ...
An experimental and kinetic modeling study of n-hexane oxidation
(Elsevier, 2015-09-11)
Ignition delay times for n-hexane oxidation have been measured in a rapid compression machine (RCM) at stoichiometric conditions and at 15 bar. Due to the high reactivity of n-hexane and non-ideal experimental effects ...