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Light driven styrene epoxidation and hydrogen generation using H2O as an oxygen source in a photoelectrosynthesis cell
(Royal Society of Chemistry, 2015-10-02)
A dye-sensitized photoelectrosynthesis cell (DSPEC) has been prepared for the oxidation of alkenes to
epoxides and evolution of hydrogen using water as an oxygen source and sunlight. A Ru oxidation catalyst,
2,2+
, is ...
Synthesis of migrastatin analogues as inhibitors of tumour cell migration: Exploring structural change in and on the macrocyclic ring
(Wiley, 2015-11-04)
Migrastatin and isomigrastatin analogues have been synthesised in order to contribute to structure-activity studies on tumour cell migration inhibitors. These include macrocycles varying in ring size, functionality and ...
Sulfamerazine: Understanding the influence of slip planes in the polymorphic phase transformation through X-ray crystallographic studies and ab initio lattice dynamics
(American Chemical Society, 2015-08-28)
Understanding the polymorphism exhibited by organic active-pharmaceutical ingredients (APIs), in particular the relationships between crystal structure and the thermodynamics of polymorph stability, is vital for the ...
DNA damage and induction of apoptosis in pancreatic cancer cells by a new dinuclear bis(triazacyclonane) copper complex
(Elsevier, 2015-01-26)
The dinuclear copper(II) complex [Cu-2{bcmp(-H)}(mu-OH)](NO3)(2)center dot H2O (1, bcmp = 2,6-bis(1,4,7-triazacyclonon-1-ylmethyl)-4-methylphenol) has been synthesized and characterized by electrospray ionization mass ...
Cytotoxicity and antimicrobial activity of triorganotin(IV) complexes of phenylcyanamide prepared by sonochemical synthesis
(Elsevier, 2015-09-25)
This article describes the synthesis and characterization of novel triorganotin(IV) complexes and their potential medicinal applications. Triorganotin(IV) complexes with formulas [(SnMe3)(2)(mu-bp)(H2O)(2)], 1, and ...
The annual GiG: Groups in Galway
(NUI Galway, 2015)
The GiG (Groups in Galway) conference, and related activity, has been
running annually since 1978 and is the longest running annual international
mathematical conference on a special topic. It has its origin from the ...
Bumblebee learning and memory is impaired by chronic exposure to a neonicotinoid pesticide.
(Nature Publishing Group, 2015-11-16)
Bumblebees are exposed to pesticides applied for crop protection while foraging on treated plants, with increasing evidence suggesting that this sublethal exposure has implications for pollinator declines. The challenges ...
A refinement of a conjecture of Quillen
(Elsevier ScienceDirect, 2015-09)
We present some new results on the cohomology of a large scope of SL2 groups in degrees above the virtual cohomological dimension, yielding some partial positive results for the Quillen conjecture in rank one. We combine ...
Scaling behavior of polymers at liquid/liquid interfaces
(American Chemical Society, 2015-09-14)
The dynamics of a polymer chain confined in a soft 2D slit formed by two immiscible liquids is studied by means of molecular dynamics simulations. We show that the scaling behavior of a polymer confined between two liquids ...
Engineering recombinant antibodies for polymer biofunctionalization
(Wiley, 2015-08-18)
The attachment of recognition elements such as antibody fragments to polymeric substrates can be used to mediate cell- or protein-specific interactions. In this work, single-chain Fv (scFv) antibody fragments were isolated ...