dc.contributor.author | Perivolaris, Alexandros | |
dc.contributor.author | Stoumpos, Constantinos C. | |
dc.contributor.author | Karpinska, Jolanta | |
dc.contributor.author | Ryder, Alan G. | |
dc.contributor.author | Frost, Jamie M. | |
dc.contributor.author | Mason, Kevin | |
dc.contributor.author | Prescimone, Alessandro | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Kessler, Vadim G. | |
dc.contributor.author | Mathieson, Jennifer S. | |
dc.contributor.author | Cronin, Leroy | |
dc.contributor.author | Brechin, Euan K. | |
dc.contributor.author | Papaefstathiou, Giannis S. | |
dc.date.accessioned | 2018-09-20T16:21:28Z | |
dc.date.available | 2018-09-20T16:21:28Z | |
dc.date.issued | 2014-01-01 | |
dc.identifier.citation | Perivolaris, Alexandros; Stoumpos, Constantinos C. Karpinska, Jolanta; Ryder, Alan G.; Frost, Jamie M.; Mason, Kevin; Prescimone, Alessandro; Slawin, Alexandra M. Z.; Kessler, Vadim G.; Mathieson, Jennifer S.; Cronin, Leroy; Brechin, Euan K.; Papaefstathiou, Giannis S. (2014). A family of [ni8] cages templated by μ6-peroxide from dioxygen activation. Inorg. Chem. Front. 1 (6), 487-494 | |
dc.identifier.issn | 2052-1553 | |
dc.identifier.uri | http://hdl.handle.net/10379/13454 | |
dc.description.abstract | A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form. | |
dc.publisher | Royal Society of Chemistry (RSC) | |
dc.relation.ispartof | Inorg. Chem. Front. | |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Ireland | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ie/ | |
dc.subject | transition-metal-complexes | |
dc.subject | spectroscopic characterization | |
dc.subject | structural-characterization | |
dc.subject | peroxo intermediate | |
dc.subject | nickel(i) complex | |
dc.subject | crystal-structure | |
dc.subject | oxygen complexes | |
dc.subject | room-temperature | |
dc.subject | o-o | |
dc.subject | reactivity | |
dc.title | A family of [ni8] cages templated by μ6-peroxide from dioxygen activation | |
dc.type | Article | |
dc.identifier.doi | 10.1039/c4qi00048j | |
dc.local.publishedsource | https://pub.epsilon.slu.se/11655/7/perivolaris_a_et_al_151027.pdf | |
nui.item.downloads | 0 | |