Photochemical aryl radical cyclizations to give (e)-3-ylideneoxindoles

Gurry, Michael; Allart-Simon, Ingrid; McArdle, Patrick; Gérard, Stéphane; Sapi, Janos; Aldabbagh, Fawaz

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Date

2014-09-30

Author

Gurry, Michael

Allart-Simon, Ingrid

McArdle, Patrick

Gérard, Stéphane

Sapi, Janos

Aldabbagh, Fawaz

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Gurry, Michael; Allart-Simon, Ingrid; McArdle, Patrick; Gérard, Stéphane; Sapi, Janos; Aldabbagh, Fawaz (2014). Photochemical aryl radical cyclizations to give (e)-3-ylideneoxindoles. Molecules 19 (10), 15891-15899

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http://www.mdpi.com/1420-3049/19/10/15891/pdf

Abstract

(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts.

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http://hdl.handle.net/10379/11776

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Externally hosted open access publications with NUI Galway authors (2)

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