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Synthesis of migrastatin analogues as inhibitors of tumour cell migration: Exploring structural change in and on the macrocyclic ring
(Wiley, 2015-11-04)
Migrastatin and isomigrastatin analogues have been synthesised in order to contribute to structure-activity studies on tumour cell migration inhibitors. These include macrocycles varying in ring size, functionality and ...
Synthesis of an orthogonally protected polyhydroxylated cyclopentene from L-Sorbose
(Chemical Editorial Society (ACES) / Wiley, 2016-07-06)
The use of l-sorbose in the synthesis of functionalized cyclopentene derivatives was accomplished. These cyclopentene derivatives are related to those found in naturally occurring jatrophane frameworks and in other bioactive ...
Homo- and Heterometallic planes, chains and cubanes.
(RSC, 2013-05-24)
The synthesis, structural and magnetic characterisation of a family of homo- and heterometallic complexes constructed with the Schiff base ligands 2-iminomethyl-6-methoxy-phenol (L1H) and 2-imino-6-methoxy-phenol (L2H), ...
Progressive Decoration of a Pentanuclear Cu(II) 12-Metallocrown-4 Towards Targeted 1- and 2-D Extended Networks
(RSC, 2013-07-05)
The synthesis, structures and magnetic characterisation of a family of discrete planar pentanuclear Cu(II) 12-MC-4 metallacrowns of formulae [Cu5(L1)4(MeOH)4](ClO4)2 (1), [Cu5(L1)4(py)2](ClO4)2·py (2), [Cu5(L1)4(py)6](ClO4)2 ...
Ferromagnetic exchange in a twisted, oxime-bridged [Mn(III)2] dimer
(Royal Society of Chemistry, 2012-05-02)
The dimeric complex [MnIII2(Naphth-sao)2(Naphth-saoH)2(MeOH)2][middle dot]4MeOH (1[middle dot]4MeOH), acts as a simple model complex with which to examine the magneto-structural relationship in polymetallic, oxime-bridged ...
Old dog, new tricks: 2,2'-biphenol as a bridging and book-end ligand in discrete and extended Co(II) architectures
(RSC, 2012-02-01)
We report the first Co(ii) based discrete and extended network materials comprising the 2,2[prime or minute]-biphenol ligand. We first present the synthesis and magnetic characterisation of the Co(ii) dinuclear complexes ...
Twisted molecular magnets
(RSC, 2012-09-05)
The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([MnIII6]) and thirty trinuclear ([MnIII3]) Single-Molecule Magnets (SMMs). Deliberate, ...
Investigating the solid state hosting abilities of homo- and hetero-valent [Co-7] metallocalix[6]arenes
(RSC, 2012)
A family of homo-valent [Co(II)(7)(OH)(6)(L-1)(6)](NO3)(2)(1), [(MeOH)(2)subset of Co(II)(7)(OH)(6)(L-1)(6)](NO3)(2) (2) (where L1H = 2-iminomethyl-6-methoxyphenol) and hetero-valent [(NO3)(2)subset of Co(III)Co(II)(6)(O ...
A family of double-bowl pseudo metallocalix[6]arene discs
(RSC, 2010-03-10)
We report the synthesis and magnetic characterisation of a series of planar [M7] (M = NiII, ZnII) disc complexes [Ni7(OH)6(L1)6](NO3)2 (1), [Ni7(OH)6(L1)6](NO3)2·2MeOH (2), [Ni7(OH)6(L1)6](NO3)2·3MeNO2 (3), [Ni7(OH)6(L2) ...
What controls the magnetic interaction in bis-mu-alkoxo Mn(III) dimers? A combined experimental and theoretical exploration.
(Wiley, 2012-03-29)
The synthesis and magnetic characterisation of a series of bis-mu-alkoxide bridged MnIII dinuclear complexes of general formula [MnIII2(mu-OR)2(biphen)2(ROH)x(L)y] (where R=Me, Et; H2biphen=2,2'-biphenol and L=terminally ...