Browsing School of Chemistry (Scholarly Articles) by Author "McDonagh, Anthony W."
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Lewis acid induced anomerization of se-glycosides. Application to synthesis of alpha-Se-GalCer
McDonagh, Anthony W.; Mahon, Mary F.; Murphy, Paul V. (American Chemical Society, 2016-01-22)The TiCl4 induced anomerization of selenium glycosides of galacturonic acid derivatives is reported. The reaction was successful for galacturonic acid when various alkyl, alkenyl, alkynyl, saccharide, steroid, and lipid ... -
Synthesis of α-galactosyl ceramide analogues with an α-triazole at the anomeric carbon
McDonagh, Anthony W.; Murphy, Paul V. (Elsevier, 2014-03-16)The synthesis of 1,2,3-triazole containing analogues of a-GalCer and galacturonic acid containing Sphingomonous cell wall antigens is described. Anomerisation was used to provide the required cc-glycosyl azide precursor. ...