dc.contributor.author | Coleman, L. | |
dc.contributor.author | Varghese, S. | |
dc.contributor.author | Tripathi, O. P. | |
dc.contributor.author | Jennings, S. G. | |
dc.contributor.author | O'Dowd, C. D. | |
dc.date.accessioned | 2018-09-20T16:03:41Z | |
dc.date.available | 2018-09-20T16:03:41Z | |
dc.date.issued | 2010-01-01 | |
dc.identifier.citation | Coleman, L. Varghese, S.; Tripathi, O. P.; Jennings, S. G.; O'Dowd, C. D. (2010). Regional-scale ozone deposition to north-east atlantic waters. Advances in Meteorology , | |
dc.identifier.issn | 1687-9309,1687-9317 | |
dc.identifier.uri | http://hdl.handle.net/10379/10841 | |
dc.description.abstract | A regional climate model is used to evaluate dry deposition of ozone over the North East Atlantic. Results are presented for a deposition scheme accounting for turbulent and chemical enhancement of oceanic ozone deposition and a second non-chemical, parameterised gaseous dry deposition scheme. The first deposition scheme was constrained to account for sea-surface ozone-iodide reactions and the sensitivity of modelled ozone concentrations to oceanic iodide concentration was investigated. Simulations were also performed using nominal reaction rate derived from in-situ ozone deposition measurements and using a preliminary representation of organic chemistry. Results show insensitivity of ambient ozone concentrations modelled by the chemical-enhanced scheme to oceanic iodide concentrations, and iodide reactions alone cannot account for observed deposition velocities. Consequently, we suggest a missing chemical sink due to reactions of ozone with organic matter at the air-sea interface. Ozone loss rates are estimated to be in the range of 0.5-6 ppb per day. A potentially significant ozone-driven flux of iodine to the atmosphere is estimated to be in the range of 2.5-500M molec cm(-2) s(-1), leading to amixing-layer enhancement of organo-iodine concentrations of 0.1-22.0 ppt, with an average increase in the N.E. Atlantic of around 4 ppt per day. | |
dc.publisher | Hindawi Limited | |
dc.relation.ispartof | Advances in Meteorology | |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Ireland | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ie/ | |
dc.title | Regional-scale ozone deposition to north-east atlantic waters | |
dc.type | Article | |
dc.identifier.doi | 10.1155/2010/243701 | |
dc.local.publishedsource | http://doi.org/10.1155/2010/243701 | |
nui.item.downloads | 0 | |