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dc.contributor.authorAlzahrani, Abdullah
dc.contributor.authorMirallai, Styliana I
dc.contributor.authorChalmers, Benjamin A
dc.contributor.authorMcArdle, Patrick
dc.contributor.authorAldabbagh, Fawaz
dc.date.accessioned2018-09-20T15:59:42Z
dc.date.available2018-09-20T15:59:42Z
dc.date.issued2018-01-01
dc.identifier.citationAlzahrani, Abdullah; Mirallai, Styliana I; Chalmers, Benjamin A; McArdle, Patrick; Aldabbagh, Fawaz (2018). Synthesis of n-[(dialkylamino)methyl)]acrylamides and n-[(dialkylamino)methyl]methacrylamides from schiff base salts: useful building blocks for smart polymers. Organic & Biomolecular Chemistry 16 (22), 4108-4116
dc.identifier.issn1477-0520,1477-0539
dc.identifier.urihttp://hdl.handle.net/10379/10235
dc.description.abstractThe traditional thermal Mannich reaction is unsuitable for preparing polymerizable N-methylene amino substituted acrylamides and methacrylamides. Herein we provide a facile multi-gram high yield synthesis of these monomeric precursors to stimuli-responsive polymers by the addition of acrylamides and methacrylamides onto in situ generated or freshly isolated methylene Schiff base (iminium) salts. The X-ray crystal structure of the hydrated iminium salt, 1-(hydroxymethyl)azocan-1-ium chloride and monomer center dot HCl salt (N-[(azocan-1-yl)methyl]prop-2-enamide hydrochloride) is described.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.ispartofOrganic & Biomolecular Chemistry
dc.subjectdimethyl(methylene)ammonium iodide
dc.subjectaqueous-solution
dc.subjectmannich
dc.subjectsensitivity
dc.subjectderivatives
dc.subjectaminals
dc.subjectacid
dc.titleSynthesis of n-[(dialkylamino)methyl)]acrylamides and n-[(dialkylamino)methyl]methacrylamides from schiff base salts: useful building blocks for smart polymers
dc.typeArticle
dc.identifier.doi10.1039/c8ob00811f
dc.local.publishedsourcehttp://pubs.rsc.org/en/content/articlepdf/2018/ob/c8ob00811f
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