Browsing School of Chemistry by Author "|~|IRCSET|~|"
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Ferromagnetic exchange in a twisted, oxime-bridged [Mn(III)2] dimer
Jones, Leigh F. (Royal Society of Chemistry, 2012-05-02)The dimeric complex [MnIII2(Naphth-sao)2(Naphth-saoH)2(MeOH)2][middle dot]4MeOH (1[middle dot]4MeOH), acts as a simple model complex with which to examine the magneto-structural relationship in polymetallic, oxime-bridged ... -
Impact of pig slurry amendments on phosphorus, suspended sediment and metal losses in laboratory runoff boxes under simulated rainfall
O'Flynn, C. J.; Healy, Mark G. (Elsevier, 2012)Losses of phosphorus (P) when pig slurry applications to land are followed by a rainfall event or losses from soils with high P contents can contribute to eutrophication of receiving waters. The addition of amendments to ... -
Monitoring cell culture media degradation using surface enhanced Raman scattering (SERS) spectroscopy
Calvet, Amandine; Ryder, Alan G. (Elsevier (Science Direct), 2014-06-13)The quality of the cell culture media used in biopharmaceutical manufacturing is a crucial factor affecting bioprocess performance and the quality of the final product. Due to their complex composition these media are ... -
Old dog, new tricks: 2,2'-biphenol as a bridging and book-end ligand in discrete and extended Co(II) architectures
Berg, Nelly; Jones, Leigh F. (RSC, 2012-02-01)We report the first Co(ii) based discrete and extended network materials comprising the 2,2[prime or minute]-biphenol ligand. We first present the synthesis and magnetic characterisation of the Co(ii) dinuclear complexes ... -
What controls the magnetic interaction in bis-mu-alkoxo Mn(III) dimers? A combined experimental and theoretical exploration.
Berg, Nelly; Jones, Leigh F. (Wiley, 2012-03-29)The synthesis and magnetic characterisation of a series of bis-mu-alkoxide bridged MnIII dinuclear complexes of general formula [MnIII2(mu-OR)2(biphen)2(ROH)x(L)y] (where R=Me, Et; H2biphen=2,2'-biphenol and L=terminally ...