Browsing by Subject "Zirconium"
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GaIII and ZrIV Complexes as Phosphatase Analogues
(2011-11-16)In purple acid phosphatase (PAP)-catalysed phosphate monoester hydrolysis, it is accepted that the ferric ion of the active site can mediate the reaction through Lewis acid activation of the substrate and through nucleophilic ... -
Rapid hydrolysis of phosphate monoesters by zirconium(IV) complexes in neutral solution
(2012)Three zirconium(IV) complexes (1-3) with mono- and dinucleating tripodal ligands are reported that promote the hydrolysis of the phosphate monoesters p-nitrophenyl phosphate (NPP) and phenyl phosphate (PP) in neutral ...